Let us analyze the given conditions step by step.
Step 1: Represent the vector $\vec{v}$
Define:
$\vec{v} = \vec{a} + \vec{b} + \hat{i}$.
Substitute the given values of $\vec{a}$ and $\vec{b}$:
$\vec{v} = (2\hat{i} + 5\hat{j} - \hat{k}) + (2\hat{i} - 2\hat{j} + 2\hat{k}) + \hat{i}$.
Simplify:
$\vec{v} = (2 + 2 + 1)\hat{i} + (5 - 2)\hat{j} + (-1 + 2)\hat{k} = 5\hat{i} + 3\hat{j} + \hat{k}$.
Step 2: Represent $\vec{c} + \hat{i}$ as $\vec{p}$
Define:
$\vec{p} = \vec{c} + \hat{i}$.
Step 3: Apply the cross-product condition
The condition is:
$\vec{p} \times \vec{v} = \vec{a} \times \vec{p}$.
Rearrange:
$\vec{p} \times \vec{v} - \vec{p} \times \vec{a} = \vec{0}$.
Using the distributive property of the cross product:
$\vec{p} \times (\vec{v} - \vec{a}) = \vec{0}$.
Thus, $\vec{p}$ must be parallel to $\vec{v} - \vec{a}$, which implies:
$\vec{p} = \lambda (\vec{v} - \vec{a})$, where $\lambda$ is a scalar.
Step 4: Substitute $\vec{v} - \vec{a}$
Calculate $\vec{v} - \vec{a}$:
$\vec{v} - \vec{a} = (5\hat{i} + 3\hat{j} + \hat{k}) - (2\hat{i} + 5\hat{j} - \hat{k})$.
Simplify:
$\vec{v} - \vec{a} = (5 - 2)\hat{i} + (3 - 5)\hat{j} + (1 - (-1))\hat{k} = 3\hat{i} - 2\hat{j} + 2\hat{k}$.
Thus:
$\vec{p} = \lambda (3\hat{i} - 2\hat{j} + 2\hat{k})$.
Step 5: Use the dot-product condition
The condition $\vec{a} \cdot \vec{c} = -29$ can be written as:
$\vec{a} \cdot (\vec{p} - \hat{i}) = -29$.
Substitute $\vec{p} = \lambda (3\hat{i} - 2\hat{j} + 2\hat{k})$:
$\vec{a} \cdot (\lambda (3\hat{i} - 2\hat{j} + 2\hat{k}) - \hat{i}) = -29$.
Expand:
$\vec{a} \cdot (\lambda 3\hat{i} - \lambda 2\hat{j} + \lambda 2\hat{k} - \hat{i}) = -29$.
Substitute $\vec{a} = 2\hat{i} + 5\hat{j} - \hat{k}$:
$\vec{a} \cdot (3\lambda \hat{i} - 2\lambda \hat{j} + 2\lambda \hat{k} - \hat{i}) = -29$.
Simplify:
$(2)(3\lambda) + (5)(-2\lambda) + (-1)(2\lambda) - (2)(1) = -29$.
Thus:
$6\lambda - 10\lambda - 2\lambda - 2 = -29$.
Solve for $\lambda$:
$-6\lambda - 2 = -29 \implies -6\lambda = -27 \implies \lambda = \frac{27}{6} = -\frac{1}{2}$.
Step 6: Compute $\vec{c}$
Substitute $\vec{c} = \vec{p} - \hat{i}$:
$\vec{c} = \lambda (3\hat{i} - 2\hat{j} + 2\hat{k}) - \hat{i}$.
Simplify:
$\vec{c} = -\frac{1}{2}(3\hat{i} - 2\hat{j} + 2\hat{k}) - \hat{i}$.
$\vec{c} = -\frac{3}{2}\hat{i} + \hat{j} - \hat{k} - \hat{i}$.
Combine terms:
$\vec{c} = -\frac{5}{2}\hat{i} + \hat{j} - \hat{k}$.
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,