Question:

Lattice enthalpy and enthalpy of solution of NaCl are 788 kJ mol\(-1\), and 4 kJ mol\(-1\), respectively.
The hydration enthalpy of NaCl is :

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Enthalpy of solution = lattice enthalpy + hydration enthalpy (lattice enthalpy taken as the energy needed to break the lattice, a positive quantity).
Updated On: Nov 5, 2026
  • \(-780\) kJ mol\(-1\)
  • \(-784\) kJ mol\(-1\)
  • 780 kJ mol\(-1\)
  • 784 kJ mol\(-1\)
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The Correct Option is B

Solution and Explanation

Dissolving an ionic solid is a two-step cycle: NaCl(s) \(\to\) \(\mathrm{Na^{+}(g) + Cl^{-}(g)}\) (needs the lattice enthalpy), followed by hydration of the gaseous ions.
\(\Delta H_{sol} = \Delta H_{lattice} + \Delta H_{hyd}\)
\(4 = 788 + \Delta H_{hyd}\)
\(\Delta H_{hyd} = 4 - 788 = -784\) kJ mol\(-1\)
Answer: (2) \(-784\) kJ mol\(-1\)
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