In which of the following does the central atom exhibit an oxidation state of +2 ?
K2 [Ni(CN)4 ]
K3 [Fe(CN)6]
[Fe(C2O4)3 ]3-
[Cu(NH3)4 ]2+
K2(Ni(CN)4):
In this the anion will have a charge of -2 as 2K+ is present.
Then the charge on the central atom that is Ni can be calculated:
CN has a charge of -1, therefore Nickel x
x+4(-1) = -2
x = +2
[Cu(NH3)4 ]2+:
In this NH3 is neutral thus has a charge of 0 and the compound has an overall charge of +2.
Therefore the charge on the central atom that is Cu is +2.
Given below are two statements:
Statement I: The number of species among \( SF_4 \), \( NH_4^+ \), \( [NiCl_4]^{2-} \), \( XeF_4 \), \( [PtCl_4]^{2-} \), \( SeF_4 \) and \( [Ni(CN)_4]^{2-} \), that have tetrahedral geometry is 3.
Statement II: In the set \( [NO_2] \), \( BeH_2 \), \( BF_3 \), \( AlCl_3 \), all the molecules have incomplete octet around the central atom.
In the light of the above statements, choose the correct answer from the options given below: