Concept:
The Kraft process is the most common chemical pulping method used to separate cellulose fibers from wood by dissolving lignin.
Step 1:
Wood contains cellulose fibers bound together by lignin.
Pulping removes lignin and frees the fibers.
Step 2:
The cooking liquor in the Kraft process mainly contains
sodium hydroxide (NaOH) and sodium sulfide (Na$_2$S).
Step 3:
These chemicals break down lignin while preserving useful cellulose fibers.
Step 4:
Calcium bisulfite belongs to sulfite process,
while sulfuric acid and ammonium hydroxide are not standard Kraft pulping chemicals.
Step 5:
Hence, the Kraft process uses sodium hydroxide and sodium sulfide.