Step 1: Set up the deduction as an elimination over the six rounds for Vitezlav Vesely's best (medal winning) throw.
There are six candidate rounds, 1 through 6. Each clue removes one or more of these candidates until only one remains.
Step 2: Apply clue (i).
Clue (i) states that in rounds 1 and 2, only Neeraj Chopra produced a medal winning performance (his eventual gold medal throw came in round 2), and explicitly says the other two athletes, which includes Vitezlav Vesely, did not have any medal winning throws in these two rounds. This directly removes rounds 1 and 2 as possibilities for Vitezlav's best throw.
Remaining candidates: 3, 4, 5, 6.
Step 3: Apply clue (ii).
Clue (ii) states the round 6 throw by Vitezlav Vesely was a foul and was not considered for scoring at all, so it cannot be his best counted throw.
Remaining candidates: 3, 4, 5.
Step 4: Apply clue (iii).
Clue (iii) states that after four rounds Vitezlav was already in second (medal) position, and that he could not improve upon his best throw in the rounds that followed (rounds 5 and 6). This means his best throw was already achieved within rounds 1 to 4, so round 5 cannot be where his best throw occurred.
Remaining candidates: 3, 4.
Step 5: Apply clue (iv).
Clue (iv) states that in round 4 specifically, it was Jakub Vadlejch, not Vitezlav Vesely, who recorded the best throw of that round among the three athletes. Since round 4 is singled out as belonging to Jakub's performance, round 4 is not the round of Vitezlav's own best throw.
Remaining candidate: 3.
Step 6: Conclude.
The only round consistent with all four clues is round 3, so Vitezlav Vesely's best throw occurred in the third round.
\[ \boxed{\text{Third}} \]