(i) We consider the arrangements by taking $2$ particular children together as one and hence the $4$ children can be arranged in $4! = 24$ ways. Again two particular children taken together can be arranged in two ways. Therefore, there are $24 \times 2 = 48$ total ways of arrangement.
(ii) Among the $5! = 120$ permutations of $5$ children, there are $48$ in which two children are together. In the remaining $120 - 48 = 72$ permutations, two particular children are never together.