Chromium in chromyl chloride (CrO$_2$Cl$_2$):
Oxidation state of Cr is +6.
Electronic configuration: Cr$^{6+}$ = [Ar] 3d$^0$ 4s$^0$, meaning there are zero d-electrons.
Manganese in Mn (VII):
Oxidation state of Mn is +7.
Electronic configuration: Mn$^{7+}$ = [Ar] 3d$^0$ 4s$^0$, also zero d-electrons.
Thus, the number of d-electrons is the same for Cr in CrO$_2$Cl$_2$ and Mn in Mn (VII).
\(t_{100\%}\) is the time required for 100% completion of a reaction, while \(t_{1/2}\) is the time required for 50% completion of the reaction. Which of the following correctly represents the relation between \(t_{100\%}\) and \(t_{1/2}\) for zero order and first order reactions respectively
One mole of an alkane (\(x\)) requires 8 mole oxygen for complete combustion. Sum of number of carbon and hydrogen atoms in the alkane (\(x\)) is ______.
For reaction \(A \rightarrow P\), rate constant \(k = 1.5 \times 10^3\ s^{-1}\) at \(27^\circ C\). If activation energy for the above reaction is \(60\ kJ\ mol^{-1}\), then the temperature (in \(^{\circ}C\)) at which rate constant \(k = 4.5 \times 10^3\ s^{-1}\) is ______. (Nearest integer) \[ \text{Given: } \log 2 = 0.30,\ \log 3 = 0.48,\ R = 8.3\ J\ K^{-1}\ mol^{-1},\ \ln 10 = 2.3 \]
Given below are the quantum numbers for 4 electrons.
A. n=3, l=2, ml=1,ms=+\(\frac{1}{2}\)
B. n=4, l=1, ml=0,ms=+\(\frac{1}{2}\)
C. n=4, l=2, ml=–2,ms=–\(\frac{1}{2}\)
D. n=3, l=1, ml=–1,ms=+\(\frac{1}{2}\)
The correct order of increasing energy is