Concept:
Three-layer (Hoopes) refining is used for purification of aluminium. It is based on:
- difference in density of molten layers
- immiscibility between layers
- electrorefining principle
The system forms:
- bottom layer (heaviest alloy)
- middle layer (impure Al)
- top layer (pure Al)
Step 1: Role of alloying metal.
Impure aluminium is alloyed with a heavy metal to increase density so that it forms the bottom layer.
Step 2: Selection of metal.
Copper is used because:
- it increases density significantly
- forms a heavy molten alloy with aluminium
- remains stable at operating temperature
Final Answer:
\[
\boxed{\text{Copper}}
\]