Concept:
In a triangle, the sides opposite vertices \(A\), \(B\), and \(C\) are denoted by \(a\), \(b\), and \(c\) respectively.
Since the triangle is right-angled at \(C\),
\[
\angle C = 90^\circ,
\]
the side opposite the right angle, namely \(c\), is the hypotenuse.
Further, because the triangle is an isosceles right-angled triangle, the two legs containing the right angle are equal in length. Therefore,
\[
a=b.
\]
The hypotenuse can then be obtained using the Pythagorean theorem.
Step 1: Use the property of an isosceles right triangle.
Since the triangle is isosceles and right-angled at \(C\),
\[
a=b.
\]
Given,
\[
a=2.
\]
Therefore,
\[
b=2.
\]
Step 2: Apply the Pythagorean theorem.
For a right triangle,
\[
c^2=a^2+b^2.
\]
Substituting \(a=2\) and \(b=2\),
\[
c^2=2^2+2^2.
\]
\[
c^2=4+4=8.
\]
Step 3: Calculate the hypotenuse.
Taking square roots on both sides,
\[
c=\sqrt8
=\sqrt{4\times2}
=2\sqrt2.
\]
Step 4: Write the values of \(b\) and \(c\).
We obtained
\[
b=2
\]
and
\[
c=2\sqrt2.
\]
Conclusion:
Hence, the values of \(b\) and \(c\) respectively are
\[
\boxed{2,\;2\sqrt2}.
\]
Therefore, the correct option is
\[
\boxed{(D)}.
\]