Concept:
In the kinematic analysis of mechanisms, an instantaneous center (I-center) is a virtual point common to two bodies that has the same instantaneous velocity in both magnitude and direction. For a kinematic mechanism composed of a fixed number of rigid links, the total number of instantaneous centers $N$ corresponds to the number of unique pairs that can be formed from those links. Mathematically, this is found using the combinations formula $N = \binom{n}{2}$:
\[
N = \frac{n(n - 1)}{2}
\]
where $n$ represents the total number of links inside the mechanism.
Step 1: Evaluating the formula for the given number of links.
The problem states that the mechanism contains five links:
\[
n = 5
\]
Substitute $n = 5$ into our combinations equation:
\[
N = \frac{5 \times (5 - 1)}{2}
\]
Step 2: Simplifying the arithmetic computation.
\[
N = \frac{5 \times 4}{2} = \frac{20}{2} = 10
\]
Thus, a 5-link mechanism contains exactly $10$ unique instantaneous centers of rotation. This matches Option (A).