Step 1: Find the earliest position "learn" can occupy.
The first word is "clean" (5 letters: c-l-e-a-n). To reach "learn" (5 letters: l-e-a-r-n), compare the two words. Removing the leading "c" from "clean" gives "lean" (4 letters: l-e-a-n), and then adding an "r" before the final "n" gives "learn" (l-e-a-r-n). That is two moves: delete "c", then add "r". Since two separate moves are needed, "learn" cannot appear as the second word (only one move away from "clean"); the earliest it can appear is the THIRD word, after "clean" then "lean" then "learn". So any option built around "second" as a possible position is automatically wrong.
Step 2: Confirm "learn" as the third word.
Chain: clean (delete "c") lean (add "r") learn. Two operations, delete then add, different from each other, satisfying the no-repeat rule. Alphabetically, "clean" comes before "lean", which comes before "learn", so the order climbs correctly. Position THREE is valid.
Step 3: Push "learn" to the fourth position.
Insert one extra word before reaching "learn" while still using a fresh operation each step. Chain: clean (replace "n" with "r") clear (delete "c") lear (add "n") learn. That is replace, delete, add: three different consecutive operations, and "clean", "clear", "lear", "learn" climb alphabetically in that order. Position FOUR is valid.
Step 4: Push "learn" to the fifth position.
Insert two extra words before "learn". Chain: clean (replace "c" with "d") dlean (delete "d") lean (replace "n" with "r") lear (add "n") learn. Operations used: replace, delete, replace, add, each different from the one right before it, and the words climb alphabetically: clean, dlean, lean, lear, learn. Position FIVE is valid.
Step 5: Push "learn" to the sixth (last) position.
Insert three extra words before "learn". Chain: clean (replace "c" with "d") dlean (add a letter, for example "p") dleapn (replace "d" with "e") eleapn (delete "p") leapn (replace "p" with "r") learn. Operations: replace, add, replace, delete, replace, and each is different from its immediate neighbour, while the six words climb alphabetically at every step. Position SIX is valid, meaning "learn" can be the sixth and final word too.
Final Answer:
"Learn" can occupy the third, fourth, fifth, or sixth position, but never the first or second.
\[ \boxed{\text{Third, fourth, fifth, sixth}} \]