When two unbiased coins are tossed, the possible outcomes are:
\[
{HH, HT, TH, TT}
\]
There are 4 possible outcomes in total. Now, we are asked to find the probability of getting at least one head. The only outcome that does not satisfy this condition is "TT" (both tails). Hence, the complementary event is getting "TT", which occurs with probability:
\[
P({TT}) = \frac{1}{4}
\]
So, the probability of having at least one head is:
\[
P({at least one head}) = 1 - P({TT}) = 1 - \frac{1}{4} = \frac{3}{4} = 0.75
\]
Thus, the correct answer is option (D) 0.75.