Step 1: Find the side length from volume.
For a cube with side \(a\), volume \(V=a^3\). Given \(a^3=125 \Rightarrow a=\sqrt[3]{125}=5\ \text{cm}.\) Step 2: Write the space diagonal of a cube.
Space diagonal \(d=a\sqrt{3} = 5\sqrt{3}\ \text{cm}.\) Step 3: Form the required ratio (side : diagonal).
\[
a:d = 5 : 5\sqrt{3} = 1 : \sqrt{3}.
\]