If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the reaction
${Zn(s) + cu^{2+} (aq) <=> Zn^{2+} (aq) + Cu(s)}$ at 300 K is approximately.
${(R = 8 \; JK^{-1} \; mol^{-1} , F = 96000 \; C \; mol^{-1})}$
- $e^{160}$
- $e^{320}$
- $e^{ - 160}$
- $e^{ - 80}$
The Correct Option is A
Solution and Explanation
${Ink = \frac{ n \times F \times E^{\circ}}{R \times T} = \frac{2 \times 96000 \times 2}{8 \times 300}} $
Ink = 160
$k = e^{160}$
Top JEE Main Chemistry Questions
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)- At equilibrium the concentrations of and in a sealed vessel at . What will be for the reaction
- Find out the major products from the following reactions
Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are
- The correct order of atomic radii is:
Top JEE Main Equilibrium Constant Questions
37.8 g \( N_2O_5 \) was taken in a 1 L reaction vessel and allowed to undergo the following reaction at 500 K: \[ 2N_2O_5(g) \rightarrow 2N_2O_4(g) + O_2(g) \]
The total pressure at equilibrium was found to be 18.65 bar. Then, \( K_p \) is: Given: \[ R = 0.082 \, \text{bar L mol}^{-1} \, \text{K}^{-1} \]- Match the LIST-I with LIST-II
Choose the correct answer from the options given below:
Top JEE Main Questions
- In a hydrogen like atom, when an electron jumps from the $M$ - shell to the $L$ - shell, the wavelength of emitted radiation is $\lambda$. If an electron jumps from $N$-shell to the $L$-shell, the wavelength of emitted radiation will be :
- Two masses $m$ and $\frac{m}{2}$ are connected at the two ends of a massless rigid rod of length $l$. The rod is suspended by a thin wire of torsional constant $k$ at the centre of mass of the rod-mass system(see figure). Because of torsional constant $k$, the restoring torque is $\tau =k\theta$ for angular displacement $\theta$. If the rod is rota ted by $\theta_0$ and released, the tension in it when it passes through its mean position will be:
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)- The value of is
- The number of terms of an is even. The sum of the odd terms is and of the even terms is . The last term exceeds the first by . Then the number of terms in the series is ______.
Concepts Used:
Equilibrium Constant
The equilibrium constant may be defined as the ratio between the product of the molar concentrations of the products to that of the product of the molar concentrations of the reactants with each concentration term raised to a power equal to the stoichiometric coefficient in the balanced chemical reaction.
The equilibrium constant at a given temperature is the ratio of the rate constant of forwarding and backward reactions.
Equilibrium Constant Formula:
Kequ = kf/kb = [C]c [D]d/[A]a [B]b = Kc
where Kc, indicates the equilibrium constant measured in moles per litre.
For reactions involving gases: The equilibrium constant formula, in terms of partial pressure will be:
Kequ = kf/kb = [[pC]c [pD]d]/[[pA]a [pB]b] = Kp
Where Kp indicates the equilibrium constant formula in terms of partial pressures.
- Larger Kc/Kp values indicate higher product formation and higher percentage conversion.
- Lower Kc/Kp values indicate lower product formation and lower percentage conversion.
Medium Kc/Kp values indicate optimum product formation.
Units of Equilibrium Constant:
The equilibrium constant is the ratio of the concentrations raised to the stoichiometric coefficients. Therefore, the unit of the equilibrium constant = [Mole L-1]△n.
where, ∆n = sum of stoichiometric coefficients of products – a sum of stoichiometric coefficients of reactants.