Step 1: Understanding the concept of adjugate matrix.
For a square matrix \( A \) of order \( n \), the determinant of the adjugate matrix \( \text{Adj}(A) \) is related to the determinant of the matrix \( A \) by the following formula:
\[
|\text{Adj}(A)| = |A|^{n-1}
\]
Since \( A \) is a \( 2 \times 2 \) matrix, we have \( n = 2 \). Therefore,
\[
|\text{Adj}(A)| = |A|^{2-1} = |A| = 5
\]
Step 2: Conclusion.
Thus, the determinant of the adjugate matrix is \( 25 \), corresponding to option (A).