For a matrix to be symmetric, the elements on the off-diagonal must be equal. That is, the element in the \( (1,2) \)-position must be equal to the element in the \( (2,1) \)-position. In this case, the matrix \( A \) is given as:
\[
A = \begin{bmatrix}
10 & 2k + 5 \\
\end{bmatrix}
\]
For \( A \) to be symmetric, the element \( 2k + 5 \) (position \( (1,2) \)) must be equal to \( 3k - 3 \) (position \( (2,1) \)). Therefore, we set up the equation:
\[
2k + 5 = 3k - 3
\]
Now, solve for \( k \):
\[
2k + 5 = 3k - 3
5 + 3 = 3k - 2k
8 = k
\]
Thus, the value of \( k \) is 8.
Final Answer:
\[
\boxed{8}
\]