Question:

Identify the correct statements from the following:

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- PCl\(_5\) has a trigonal bipyramidal structure, where axial bonds are longer than equatorial bonds.
- Zinc and dilute HNO\(_3\) produce multiple nitrogen oxides, not just NO\(_2\).
- Rhombic sulfur is the most stable allotrope at room temperature.
- SO\(_2\) to SO\(_3\) oxidation in the Contact Process is catalyzed by V\(_2\)O\(_5\) and is an exothermic reaction.
Updated On: May 4, 2026
  • In PCl\(_5\), equatorial bonds are longer than axial bonds.
  • Zinc reacts with dilute nitric acid to give NO\(_2\).
  • Rhombic sulphur is yellow in colour.
  • The reaction \( 2SO_2(g) + O_2(g) \xrightarrow{V_2O_5} 2SO_3(g) \) is exothermic.
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The Correct Option is D

Solution and Explanation

The given question asks us to identify which statements are correct from the provided options. We will analyze each statement step-by-step.

  1. Statement 1: In PCl5, equatorial bonds are longer than axial bonds.
    • PCl5 has a trigonal bipyramidal structure.
    • This structure includes 3 equatorial bonds and 2 axial bonds.
    • Typically, axial bonds are longer than equatorial bonds due to greater repulsion from more axial atoms.
    • Therefore, this statement is incorrect.
  2. Statement 2: Zinc reacts with dilute nitric acid to give NO2.
    • Generally, when zinc reacts with dilute nitric acid, it typically forms zinc nitrate, water, and nitrogen oxides such as NO or N2O.
    • NO2 is generally associated with more concentrated nitric acid reactions.
    • Therefore, this statement is incorrect.
  3. Statement 3: Rhombic sulphur is yellow in colour.
    • Rhombic sulphur, also known as alpha-sulphur, is indeed yellow in color.
    • Therefore, this statement is correct, but it is not mentioned as the correct answer choice in the given solution.
  4. Statement 4: The reaction \(2SO_2(g) + O_2(g) \xrightarrow{V_2O_5} 2SO_3(g)\) is exothermic.
    • This is the process of forming sulfur trioxide from sulfur dioxide and oxygen in the presence of a vanadium(V) oxide catalyst.
    • The reaction releases heat, making it exothermic, which matches the reported correct answer.
    • Therefore, this statement is correct.

Thus, the correct statement is: The reaction \(2SO_2(g) + O_2(g) \xrightarrow{V_2O_5} 2SO_3(g)\) is exothermic.

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