Given below are two statements :
Statement I : The pentavalent oxide of group-15 element, E2O5, is less acidic than trivalent oxide, E2O3, of the same element.
Statement II : The acidic character of trivalent oxide of group 15 elements, E2O3, decreases down the group.
In light of the above statements, choose most appropriate answer from the options given below:
Statement I : The pentavalent oxide of group-15 element, E2O5, is less acidic than trivalent oxide, E2O3, of the same element.
Statement II : The acidic character of trivalent oxide of group 15 elements, E2O3, decreases down the group.
In light of the above statements, choose most appropriate answer from the options given below:
- Both Statement I and Statement II are true
- Both Statement I and Statement II are false
- Statement I true, but Statement II is false
- Statement I false, but Statement II is true
The Correct Option is D
Solution and Explanation
The correct answer is (D) : Statement I false, but Statement II is true.
Statement I is false, as E2O5 is more acidic than E2O3
Statement II is correct.
As +ve oxidation state increases, EN of element increases hence acidic character increases. Down the group, non-metallic character decreases, acidic character decreases.
Acidic character : E2O5 > E2O3 Down the group, acidic character of E2O3 decreases
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Top JEE Main p -Block Elements Questions
- $\textbf{Reduction potential of ions are given below:}$
\[ \begin{array}{ccc} \text{ClO}_4^- & \text{IO}_4^- & \text{BrO}_4^- \\ E^\circ = 1.19 \, \text{V} & E^\circ = 1.65 \, \text{V} & E^\circ = 1.74 \, \text{V} \\ \end{array} \]
The correct order of their oxidising power is: - $\textbf{Choose the correct statements about the hydrides of group 15 elements.}$
A. The stability of the hydrides decreases in the order \(\text{NH}_3 > \text{PH}_3 > \text{AsH}_3 > \text{SbH}_3 > \text{BiH}_3\)
B. The reducing ability of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
C. Among the hydrides, \(\text{NH}_3\) is a strong reducing agent while \(\text{BiH}_3\) is a mild reducing agent.
D. The basicity of the hydrides increases in the order \(\text{NH}_3 < \text{PH}_3 < \text{AsH}_3 < \text{SbH}_3 < \text{BiH}_3\)
Choose the most appropriate from the option given below: The number of oxygen atoms present in chemical formula of fuming sulphuric acid is _______.
- Identify the correct statements about p-block elements and their compounds.
(A) Non metals have higher electronegativity than metals.
(B) Non metals have lower ionisation enthalpy than metals.
(C) Compounds formed between highly reactive nonmetals and highly reactive metals are generally ionic.
(D) The non-metal oxides are generally basic in nature.
(E) The metal oxides are generally acidic or neutral in nature. Given below are two statements:
Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bond with oxygen.
Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it.
In the light of the above statements, choose the correct answer from the options given below:
Top JEE Main Questions
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Concepts Used:
P-Block Elements
- P block elements are those in which the last electron enters any of the three p-orbitals of their respective shells. Since a p-subshell has three degenerate p-orbitals each of which can accommodate two electrons, therefore in all there are six groups of p-block elements.
- P block elements are shiny and usually a good conductor of electricity and heat as they have a tendency to lose an electron. You will find some amazing properties of elements in a P-block element like gallium. It’s a metal that can melt in the palm of your hand. Silicon is also one of the most important metalloids of the p-block group as it is an important component of glass.
P block elements consist of:
- Group 13 Elements: Boron family
- Group 14 Elements: Carbon family
- Group 15 Elements: Nitrogen family
- Group 16 Elements: Oxygen family
- Group 17 Elements: Fluorine family
- Group 18 Elements: Neon family