Given below are two statements:
Statement I: The esterification of carboxylic acid with an alcohol is a nucleophilic acyl substitution.
Statement II: Electron withdrawing groups in the carboxylic acid will increase the rate of esterification reaction.
Choose the most appropriate option
Given below are two statements:
Statement I: The esterification of carboxylic acid with an alcohol is a nucleophilic acyl substitution.
Statement II: Electron withdrawing groups in the carboxylic acid will increase the rate of esterification reaction.
Choose the most appropriate option
- Both Statement I and Statement II are correct.
- Both Statement I and Statement II are incorrect.
- Statement I is correct but Statement II is incorrect.
- Statement I is incorrect but Statement II is correct.
The Correct Option is A
Solution and Explanation
The correct option is(A): Both Statement I and Statement II are correct.
Esterification of carboxylic acid with an alcohol is nucleophilic acyl substitution and presence of electron withdrawing group in the carboxylic acid increases the rate of esterification reaction.
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Concepts Used:
Acids and Bases
Acid is any hydrogen-containing substance that is capable of donating a proton (hydrogen ion) to another substance. Base is an ion or molecule capable of accepting a hydrogen ion from acid.
Physical Properties of Acids and Bases
| Physical Properties | ACIDS | BASES |
| Taste | Sour | Bitter |
| Colour on Litmus paper | Turns blue litmus red | Turns red litmus blue |
| Ions produced on dissociation | H+ | OH- |
| pH | <7 (less than 7) | >7 (more than 7) |
| Strong acids | HCl, HNO3, H2SO4 | NaOH, KOH |
| Weak Acids | CH3COOH, H3PO4, H2CO3 | NH4OH |
Chemical Properties of Acids and Bases
| Type of Reaction | Acid | Bases |
| Reaction with Metals | Acid + Metal → Salt + Hydrogen gas (H2) E.g., Zn(s)+ dil. H2SO4 → ZnSO4 (Zinc Sulphate) + H2 | Base + Metal → Salt + Hydrogen gas (H2) E.g., 2NaOH +Zn → Na2ZnO2 (Sodium zincate) + H2 |
| Reaction with hydrogen carbonates (bicarbonate) and carbonates | Metal carbonate/Metal hydrogen carbonate + Acid → Salt + Carbon dioxide + Water E.g., HCl+NaOH → NaCl+ H2O 2. Na2CO3+ 2 HCl(aq) →2NaCl(aq)+ H2O(l) + CO2(g) 3. Na2CO3+ 2H2SO4(aq) →2Na2SO4(aq)+ H2O(l) + CO2(g) 4. NaHCO3+ HCl → NaCl+ H2O+ CO2 | Base+ Carbonate/ bicarbonate → No reaction |
| Neutralisation Reaction | Base + Acid → Salt + Water E.g., NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l) | Base + Acid → Salt + Water E.g., CaO+ HCl (l) → CaCl2 (aq)+ H2O (l) |
| Reaction with Oxides | Metal oxide + Acid → Salt + Water E.g., CaO+ HCl (l) → CaCl2 (aq)+ H2O (l) | Non- Metallic oxide + Base → Salt + Water E.g., Ca(OH)2+ CO2 → CaCO3+ H2O |
| Dissolution in Water | Acid gives H+ ions in water. E.g., HCl → H+ + Cl- HCl + H2O → H3O+ + Cl– | Base gives OH- ions in water. |
Read more on Acids, Bases and Salts