Question:

Given below are two statements:
Statement I: Sodium dichromate and potassium dichromate are classified as primary standards in titrimetric analysis.
Statement II: Phenolphthalein is a weak base, therefore it dissociates in acidic medium.

Updated On: Apr 12, 2026
  • Both Statement I and Statement II are true
  • Both Statement I and Statement II are false
  • Statement I is true but Statement II is false
  • Statement I is false but Statement II is true
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the Question:
We need to evaluate statements regarding primary standards and acid-base indicators.
Step 2: Detailed Explanation:
- Statement I: Potassium dichromate (\(K_2Cr_2O_7\)) is a primary standard because it can be obtained in high purity and is non-hygroscopic. However, Sodium dichromate (\(Na_2Cr_2O_7\)) is hygroscopic (absorbs moisture) and therefore cannot be used as a primary standard. This makes the statement false.
- Statement II: Phenolphthalein is a weak organic acid, not a base. It dissociates in basic medium to give a pink color. In acidic medium, the dissociation is suppressed by the common ion effect, remaining colorless. This makes the statement false.
Step 3: Final Answer:
Both statements are false.
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