Given below are two statements :
Statement I : o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.
Statement II : o-Nitrophenol has high melting due to hydrogen bonding.
In the light of the above statements, choose the most appropriate answer from the options given below :
Statement I : o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.
Statement II : o-Nitrophenol has high melting due to hydrogen bonding.
In the light of the above statements, choose the most appropriate answer from the options given below :
Show Hint
- Both Statement I and Statement II are true
- Statement I is true but Statement II is false
- Statement I is false but Statement II is true
- Both Statement I and Statement II are false
The Correct Option is B
Solution and Explanation
Statement II: because the H-bonding is intramolecular and not intermolecular, there is no molecular association, and o-nitrophenol has a low melting point (318 K) compared with p-nitrophenol (387 K), which has intermolecular H-bonding. So Statement II is FALSE.
Answer: (2) Statement I is true but Statement II is false
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