Given below are two statements:
Statement I: 
Aniline can be synthesized from 
using simpler reagents in the order
i) Acidic KMnO4,
ii) Ammonia,
iii) Bromine and alkali
Statement II: 
Aniline can be converted into 
using reagents in the order
i) Bromine-H2O
ii) NaNO2/HCl (0 - 5 C)
(iii) H3PO2.
In the light of the above statements, choose the correct answer from the options given below:
Given below are two statements:
Statement I: Aniline can be synthesized from using simpler reagents in the order
i) Acidic KMnO4,
ii) Ammonia,
iii) Bromine and alkali
Statement II: Aniline can be converted into using reagents in the order
i) Bromine-H2O
ii) NaNO2/HCl (0 - 5 C)
(iii) H3PO2.
In the light of the above statements, choose the correct answer from the options given below:
Show Hint
- Statement I is false but Statement II is true
- Both Statement I and Statement II are false
- Statement I is true but Statement II is false
- Both Statement I and Statement II are true
The Correct Option is D
Solution and Explanation
Statement II: Aniline reacts with Bromine water to form 2,4,6-tribromoaniline (white ppt). Diazotization ($NaNO_2/HCl$) converts $-NH_2$ to $-N_2^+ Cl^-$. Reduction with $H_3PO_2$ replaces the diazonium group with H, yielding 1,3,5-tribromobenzene. This is a valid sequence.
Both statements are correct.
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