Step 1: Recall the definition of the Laplace transform.
For a function \(f(t)\) defined for \(t \geq 0\), the Laplace transform is
\[
\mathcal{L}[f(t)] = F(s) = \int_0^{\infty} e^{-st} f(t)\, dt
\]
This integral turns a function of time \(t\) into a function of the complex variable \(s\), which is what makes it useful for solving differential equations.
Step 2: Substitute the given function.
Here \(f(t) = e^{-at}\), so
\[
F(s) = \int_0^{\infty} e^{-st} e^{-at}\, dt
\]
Since both terms have the same base \(e\), we add the exponents:
\[
F(s) = \int_0^{\infty} e^{-(s+a)t}\, dt
\]
Step 3: Evaluate the integral.
This is a standard exponential integral. Using \(\int e^{kt}\,dt = \dfrac{e^{kt}}{k}\) with \(k = -(s+a)\),
\[
F(s) = \left[\frac{e^{-(s+a)t}}{-(s+a)}\right]_0^{\infty}
\]
Provided \(s+a > 0\), the term \(e^{-(s+a)t}\) goes to \(0\) as \(t \to \infty\), so only the lower limit survives:
\[
F(s) = 0 - \left(\frac{1}{-(s+a)}\right) = \frac{1}{s+a}
\]
Step 4: Check the other options.
(A) \(1/(s-a)\): This is the transform of \(e^{+at}\), not \(e^{-at}\). Incorrect.
(B) \(s/(s^2+a^2)\): This is the standard Laplace transform of \(\cos(at)\). Incorrect.
(C) \(a/(s^2+a^2)\): This is the standard Laplace transform of \(\sin(at)\). Incorrect.
Step 5: Final conclusion.
The Laplace transform of \(e^{-at}\) is
\[
\boxed{F(s) = \frac{1}{s+a}}
\]
Hence, the correct option is (D).