For the system of equations to have no solution, the two lines must be parallel. This occurs when the coefficients of \( x \) and \( y \) in both equations are proportional.
The first equation is:
\[
2x + 3y = 12.
\]
The second equation is:
\[
4x + ky = 24.
\]
To find the condition for no solution, we compare the ratios of the coefficients of \( x \) and \( y \) in both equations. The coefficients of \( x \) in the two equations are \( 2 \) and \( 4 \), and the coefficients of \( y \) are \( 3 \) and \( k \).
For the lines to be parallel, the ratios of the coefficients of \( x \) and \( y \) must be equal. Therefore, we set up the equation:
\[
\frac{2}{4} = \frac{3}{k}.
\]
Simplifying the left-hand side:
\[
\frac{1}{2} = \frac{3}{k}.
\]
Now, cross-multiply to solve for \( k \):
\[
1 \times k = 2 \times 3
\Rightarrow
k = 6.
\]
Thus, the value of \( k \) that makes the two lines parallel, and thus ensures no solution for the system of equations, is:
\[
k = 6.
\]