
Monocyclic compounds $ P, Q, R $ and $ S $ are the major products formed in the reaction sequences given below.
The product having the highest number of unsaturated carbon atom(s) is:
For the reaction sequence given below, the correct statement(s) is(are): 
Consider a reaction $ A + R \rightarrow Product $. The rate of this reaction is measured to be $ k[A][R] $. At the start of the reaction, the concentration of $ R $, $[R]_0$, is 10-times the concentration of $ A $, $[A]_0$. The reaction can be considered to be a pseudo first order reaction with assumption that $ k[R] = k' $ is constant. Due to this assumption, the relative error (in %) in the rate when this reaction is 40% complete, is ____. [$k$ and $k'$ represent corresponding rate constants]

| List-I | List-II | ||
| (P) | (-)-1-Bromo-2-ethylpentane ![]() (single enantiomer) | (1) | Inversion of configuration |
| (Q) | (-)-2-Bromopentane ![]() (single enantiomer) | (2) | Retention of configuration |
| (R) | (-)-3- Bromo-3-methylhexane ![]() (single enantiometer) | (3) | Mixture of enantiomers |
| (S) | ![]() (single enantiometer) | (4) | Mixture of structural isomers |
| (5) | Mixture of diastereomers |
Match the reactions (in the given stoichiometry of the reactants) in List-I with one of their products given in List-II and choose the correct option.
List-I | List-II | ||
| (P) | P2O3 + 3H2O → | (1) | P(O)(OCH3)Cl2 |
| (Q) | P4 + 3NaOH + 3H2O → | (2) | H3PO3 |
| (R) | PCl5 + CH3COOH → | (3) | PH3 |
| (S) | H3PO2 + 2H2O + 4AgNO3 → | (4) | POCl3 |
| (5) | H3PO4 |

| List-I | List-II | ||
| (P) | \(t^6_{2g} e^0_g\) | (1) | \( [Fe(H_2O)_6]^{2+}\) |
| (Q) | \(t^3_{2g} e^2_g\) | (2) | \( [Mn(H_2O)_6]^{2+}\) |
| (R) | \(e^2t^3_{2}\) | (3) | \( [Co(NH_3)_6]^{3+}\) |
| (S) | \(t^4_{2g} e^2_g\) | (4) | \([FeCl_4]^-\) |
| (5) | \( [CoCl_4]^{2-}\) |
Monocyclic compounds $ P, Q, R $ and $ S $ are the major products formed in the reaction sequences given below.
The product having the highest number of unsaturated carbon atom(s) is:
For the reaction sequence given below, the correct statement(s) is(are): 
Consider a reaction $ A + R \rightarrow Product $. The rate of this reaction is measured to be $ k[A][R] $. At the start of the reaction, the concentration of $ R $, $[R]_0$, is 10-times the concentration of $ A $, $[A]_0$. The reaction can be considered to be a pseudo first order reaction with assumption that $ k[R] = k' $ is constant. Due to this assumption, the relative error (in %) in the rate when this reaction is 40% complete, is ____. [$k$ and $k'$ represent corresponding rate constants]
Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated.
Stoichiometry helps us determine how much substance is needed or is present. Things that can be measured are;
The Stoichiometric coefficient of any given component is the number of molecules and/or formula units that participate in the reaction as written.
The mass of one mole of a substance in grams is called molar mass. The molar mass of one mole of a substance is numerically equal to the atomic/molecular formula mass.