Concept:
For a regular hexagon,
\[
\text{distance from centre to each vertex}=L.
\]
If identical charges are placed at all six vertices, the net electric field at the centre is zero.
Step 1: Use the symmetry argument.
Imagine a sixth charge \(+q\) is placed at the missing vertex.
Then,
\[
\vec E_1+\vec E_2+\cdots+\vec E_6=0.
\]
Hence,
\[
\vec E_{\text{five charges}}
=
-\vec E_{\text{missing charge}}.
\]
Therefore the magnitude of the resultant electric field equals the field due to one charge.
Step 2: Calculate the field at the centre due to one vertex charge.
\[
E
=
\frac{1}{4\pi\varepsilon_0}
\frac{q}{L^2}.
\]
Step 3: Find the force on the charge \(-q\).
\[
F=qE
\]
\[
=
q
\left(
\frac{1}{4\pi\varepsilon_0}
\frac{q}{L^2}
\right)
\]
\[
=
\frac{1}{4\pi\varepsilon_0}
\frac{q^2}{L^2}.
\]
\[\begin{aligned}
\boxed{
F=
\frac{1}{4\pi\varepsilon_0}
\left(\frac{q}{L}\right)^2
}
\end{aligned}\]
Hence, option \(\mathbf{(A)}\) is correct.