Let $\vec a = 2\hat i + \hat j - 2\hat k$, $\vec b = \hat i + \hat j$ and $\vec c = \vec a \times \vec b$. Let $\vec d$ be a vector such that $|\vec d - \vec a| = \sqrt{11}$, $|\vec c \times \vec d| = 3$ and the angle between $\vec c$ and $\vec d$ is $\frac{\pi}{4}$. Then $\vec a \cdot \vec d$ is equal to
200 ml of an aqueous solution contains 3.6 g of Glucose and 1.2 g of Urea maintained at a temperature equal to 27$^{\circ}$C. What is the Osmotic pressure of the solution in atmosphere units?
Given Data R = 0.082 L atm K$^{-1}$ mol$^{-1}$
Molecular Formula: Glucose = C$_6$H$_{12}$O$_6$, Urea = NH$_2$CONH$_2$