A temperature difference can generate e.m.f. in some materials. Let $ S $ be the e.m.f. produced per unit temperature difference between the ends of a wire, $ \sigma $ the electrical conductivity and $ \kappa $ the thermal conductivity of the material of the wire. Taking $ M, L, T, I $ and $ K $ as dimensions of mass, length, time, current and temperature, respectively, the dimensional formula of the quantity $ Z = \frac{S^2 \sigma}{\kappa} $ is:
An ideal monatomic gas of $ n $ moles is taken through a cycle $ WXYZW $ consisting of consecutive adiabatic and isobaric quasi-static processes, as shown in the schematic $ V-T $ diagram. The volume of the gas at $ W, X $ and $ Y $ points are, $ 64 \, \text{cm}^3 $, $ 125 \, \text{cm}^3 $ and $ 250 \, \text{cm}^3 $, respectively. If the absolute temperature of the gas $ T_W $ at the point $ W $ is such that $ n R T_W = 1 \, J $ ($ R $ is the universal gas constant), then the amount of heat absorbed (in J) by the gas along the path $ XY $ is 
Monocyclic compounds $ P, Q, R $ and $ S $ are the major products formed in the reaction sequences given below.
The product having the highest number of unsaturated carbon atom(s) is:
For the reaction sequence given below, the correct statement(s) is(are): 
Consider a reaction $ A + R \rightarrow Product $. The rate of this reaction is measured to be $ k[A][R] $. At the start of the reaction, the concentration of $ R $, $[R]_0$, is 10-times the concentration of $ A $, $[A]_0$. The reaction can be considered to be a pseudo first order reaction with assumption that $ k[R] = k' $ is constant. Due to this assumption, the relative error (in %) in the rate when this reaction is 40% complete, is ____. [$k$ and $k'$ represent corresponding rate constants]