Step 1: Recall exact values of \(\sin 45^\circ\) and \(\cos 45^\circ\).
We know \(\sin 45^\circ = \dfrac{1}{\sqrt{2}}\), \(\cos 45^\circ = \dfrac{1}{\sqrt{2}}\).
Step 2: Substitute into the expression.
\[
2(\sin 45^\circ - \cos 45^\circ)
= 2\left(\dfrac{1}{\sqrt{2}} - \dfrac{1}{\sqrt{2}}\right)
= 2(0)
= 0.
\]
Step 3: Conclude.
Therefore, the value is \(0\).