The system can be written as:
\[ \begin{pmatrix} \alpha & 2 & 1 & | & 1 \\ 2\alpha & 3 & 1 & | & 1 \\ 3 & \alpha & 2 & | & \beta \end{pmatrix} \]
We denote the determinant of the coefficient matrix as \( D \). Using the determinant formula for a 3x3 matrix:
\[ D = \begin{vmatrix} \alpha & 2 & 1 \\ 2\alpha & 3 & 1 \\ 3 & \alpha & 2 \end{vmatrix} \]
Expanding along the first row:
\[ D = \alpha \begin{vmatrix} 3 & 1 \\ \alpha & 2 \end{vmatrix} - 2 \begin{vmatrix} 2\alpha & 1 \\ 3 & 2 \end{vmatrix} + 1 \begin{vmatrix} 2\alpha & 3 \\ 3 & \alpha \end{vmatrix} \]
Simplifying each determinant:
\[ D = \alpha \left(3 \cdot 2 - 1 \cdot \alpha \right) - 2 \left(2\alpha \cdot 2 - 1 \cdot 3\right) + 1 \left(2\alpha \cdot \alpha - 3 \cdot 3\right) \]
\(D = \alpha(6 - \alpha) - 2(4\alpha - 3) + (2\alpha^2 - 9)\)
\(D = \alpha(6 - \alpha) - 2(4\alpha - 3) + 2\alpha^2 - 9\)
\(D = \alpha^2 - 6\alpha - 8\alpha + 6 + 2\alpha^2 - 9\)
\(D = 3\alpha^2 - 14\alpha - 3\)
To find the values of \( \alpha \) that make the determinant zero, solve:
\( 3\alpha^2 - 14\alpha - 3 = 0 \)
Using the quadratic formula:
\( \alpha = \frac{-(-14) \pm \sqrt{(-14)^2 - 4 \cdot 3 \cdot (-3)}}{2 \cdot 3} \)
\( \alpha = \frac{14 \pm \sqrt{196 + 36}}{6} \)
\( \alpha = \frac{14 \pm \sqrt{232}}{6} \)
\( \alpha = 14 \pm 15.23 \)
Thus, the two roots are \( \alpha = 4.54 \) and \( \alpha = -0.23 \).
If \( \alpha = -1 \), substitute into the matrix:
\( D = 3(-1)^2 - 14(-1) - 3 = 3 + 14 - 3 = 14 \neq 0 \)
So, the system has a unique solution for \( \alpha = -1 \), and the second equation must hold for \( \beta = 2 \) to ensure consistency.
From the above analysis, the correct answer is option (2), as it claims that there is no solution for \( \alpha = -1 \) and for all \( \beta \), which is incorrect. The system has a solution for \( \alpha = -1 \), but only when \( \beta = 2 \).
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,