Question:

Consider the following reactions \[ Al(s)+HCl(aq)\rightarrow X+A\uparrow \] \[ Al(s)+NaOH(aq)\rightarrow Y+B\uparrow \] Which of the following is are correct? I. Y is water soluble II. X is not soluble in water III. Both A and B are same

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Aluminium is amphoteric: \[ Al + Acid \rightarrow Salt + H_2 \] \[ Al + Base \rightarrow Aluminate + H_2 \]
Updated On: Jun 17, 2026
  • I only
  • I, III only
  • II, III only
  • I, II, III
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The Correct Option is B

Solution and Explanation

Concept: Aluminium is amphoteric and reacts with both acids and bases.

Step 1:
Reaction with hydrochloric acid.
\[ 2Al+6HCl \rightarrow 2AlCl_3+3H_2 \] Thus, \[ X=AlCl_3 \] and \[ A=H_2 \] Since aluminium chloride is soluble in water, statement II is false.

Step 2:
Reaction with sodium hydroxide.
\[ 2Al+2NaOH+6H_2O \rightarrow 2Na[Al(OH)_4]+3H_2 \] Thus, \[ Y=Na[Al(OH)_4] \] which is soluble in water. Therefore statement I is true.

Step 3:
Compare gases A and B.
Both reactions evolve \[ H_2 \] Hence statement III is also true.

Step 4:
Final conclusion.
Statements I and III are correct. \[ \boxed{\text{I and III only}} \]
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