Step 1: Use DTFS orthogonality.
Given $x[n]=\sum_{k=0}^{4} a_k e^{j\frac{2\pi kn}{5}}$, we have
\[
\sum_{n=0}^{4} x[n]\,e^{-j\frac{2\pi mn}{5}}=5\,a_m,\qquad m=0,1,2,3,4.
\]
Step 2: Express the sine term in exponentials.
\[
\sin\!\left(\frac{4\pi n}{5}\right)=\frac{e^{j\frac{4\pi n}{5}}-e^{-j\frac{4\pi n}{5}}}{2j}.
\]
Hence
\[
S=\sum_{n=0}^{4}x[n]\sin\!\left(\frac{4\pi n}{5}\right)
=\frac{1}{2j}\!\left(\sum_{n=0}^{4}x[n]e^{j\frac{4\pi n}{5}}-\sum_{n=0}^{4}x[n]e^{-j\frac{4\pi n}{5}}\right).
\]
Step 3: Evaluate the two sums via Step 1.
Note $e^{j\frac{4\pi n}{5}}=e^{-j\frac{2\pi(-2)n}{5}}$ corresponds to $m\equiv-2\pmod{5}=3$, while $e^{-j\frac{4\pi n}{5}}$ corresponds to $m=2$. Therefore
\[
S=\frac{1}{2j}\big(5a_3-5a_2\big)=\frac{5}{2j}(a_3-a_2).
\]
Step 4: Substitute coefficients.
$a_3=-2j$, $a_2=2j \Rightarrow a_3-a_2=-4j$. Thus
\[
S=\frac{5}{2j}.(-4j)=-10.
\]
\[
\boxed{-10}
\]