Step 1: State the general polytropic relation and what "isobaric" means.
A polytropic process is described by PV^n = constant. An isobaric process is, by definition, a process carried out at constant pressure, meaning P does not change as V changes.
Step 2: Substitute the isobaric condition into the polytropic relation.
Write the polytropic relation as P = C/V^n = C V^(-n). For P to remain independent of V, the exponent on V must vanish, that is -n = 0, giving n = 0. Substituting back confirms: with n=0, PV^0 = P = constant, exactly the isobaric condition.
Step 3: Verify the other listed special cases.
With n=1, PV = constant, the isothermal process for an ideal gas, not isobaric. As n approaches infinity, the relation collapses to V = constant, the isochoric process. When n equals the ratio of specific heats, the process becomes the reversible adiabatic process.
Step 4: Conclude.
Only n = 0 reduces PV^n = constant to P = constant, the definition of an isobaric process.
\[ \boxed{n = 0} \]