Step 1: List the minterms in binary (order \(PQRS\)).
m1 = 0001 m2 = 0010 m3 = 0011 m4 = 0100 m5 = 0101
m7 = 0111 m10 = 1010 m12 = 1100 m13 = 1101 m14 = 1110
The remaining minterms \(\{0,6,8,9,11,15\}\) are 0 (not don't-cares).
Step 2: Find the essential prime implicants by grouping.
Group \(\{1,3,5,7\}\) = \(0001,0011,0101,0111\): all have \(P=0, S=1\), with \(Q,R\) taking all four combinations -- a valid 4-cell group giving the prime implicant \(\bar{P}S\).
Group \(\{4,5,12,13\}\) = \(0100,0101,1100,1101\): all have \(Q=1,R=0\), with \(P,S\) taking all four combinations -- a valid 4-cell group giving the prime implicant \(Q\bar{R}\).
No larger implicant can be formed containing m1 (dropping any literal from \(\bar{P}S\) would pull in the 0-minterms \(m9, m11, m15\)), so \(\bar{P}S\) is essential. Similarly \(Q\bar{R}\) is the unique maximal implicant covering m4, so it is essential too.
Step 3: Determine what remains to be covered.
\(\bar{P}S\) covers \(\{1,3,5,7\}\); \(Q\bar{R}\) covers \(\{4,5,12,13\}\). Together they cover \(\{1,3,4,5,7,12,13\}\). The full minterm list is \(\{1,2,3,4,5,7,10,12,13,14\}\), so the still-uncovered minterms are \(\{2, 10, 14\}\).
Step 4: Find prime implicants for the remaining minterms \(\{2,10,14\}\) (binary \(0010, 1010, 1110\)).
These three cells all share \(R=1, S=0\), but the fourth corner of that potential 4-group, \(m6=0110\), is a 0-minterm, so no 4-cell group is possible; only pairwise groupings are valid:
- \(\{2,3\}\) (\(0010,0011\)): differ only in \(S\), giving \(\bar{P}\bar{Q}R\).
- \(\{2,10\}\) (\(0010,1010\)): differ only in \(P\), giving \(\bar{Q}R\bar{S}\).
- \(\{10,14\}\) (\(1010,1110\)): differ only in \(Q\), giving \(PR\bar{S}\).
- \(\{12,14\}\) (\(1100,1110\)): differ only in \(R\), giving \(PQ\bar{S}\).
Each of these is a genuine prime implicant: dropping any further literal always pulls in a 0-minterm such as \(m0, m6, m8, m9, m11\) or \(m15\).
Step 5: Combine to cover \(\{2,10,14\}\) with as few extra terms as possible.
No single prime implicant covers all three of \(2, 10, 14\) (Step 4), so at least 2 more terms are needed, chosen so their union covers \(\{2,10,14\}\):
(i) \(\bar{P}\bar{Q}R\{2,3\}\) plus \(PR\bar{S}\{10,14\}\): union covers \(\{2,3,10,14\} \supseteq \{2,10,14\}\). This is exactly option (B): \(\bar{P}S+Q\bar{R}+\bar{P}\bar{Q}R+PR\bar{S}\).
(ii) \(\bar{Q}R\bar{S}\{2,10\}\) plus \(PQ\bar{S}\{12,14\}\): union covers \(\{2,10,12,14\} \supseteq \{2,10,14\}\). This is exactly option (D): \(\bar{P}S+Q\bar{R}+PQ\bar{S}+\bar{Q}R\bar{S}\).
Both combinations use exactly 4 terms in total (2 essential plus 2 more), the minimum possible, since \(\{2,10,14\}\) genuinely requires 2 separate implicants to cover.
Step 6: Check options (A) and (C) for completeness.
Option (A): \(\bar{P}S + Q\bar{R} + \bar{P}\bar{Q}R + \bar{Q}R\bar{S}\) covers \(\{1,3,5,7\} \cup \{4,5,12,13\} \cup \{2,3\} \cup \{2,10\} = \{1,2,3,4,5,7,10,12,13\}\) -- this MISSES minterm 14 (no term is satisfied at \(P=1,Q=1,R=1,S=0\)). So option (A) does not equal \(F\); it is invalid.
Option (C): \(\bar{P}S + Q\bar{R} + PQ\bar{S} + PR\bar{S}\) covers \(\{1,3,5,7\} \cup \{4,5,12,13\} \cup \{12,14\} \cup \{10,14\} = \{1,3,4,5,7,10,12,13,14\}\) -- this MISSES minterm 2 (no term is satisfied at \(P=0,Q=0,R=1,S=0\)). So option (C) is also invalid.
Step 7: Conclusion.
Only options (B) and (D) are complete, minimal, all-prime-implicant sum-of-products expressions equal to \(F\).
\[ \boxed{\text{Options (B) and (D)}} \]