Aryl halides are less reactive towards nucleophilic substitution
reaction as compared to alkyl halide due to
- the formation of less stable carbonium ion
- resonance stabilisation
- longer carbon halogen bond
- $sp^2$-hybridised carbon bonded to halogen
The Correct Option is D
Solution and Explanation
carbon bearing X is $sp^2$- hybridised.
Top JEE Advanced Chemistry Questions
- Adsorption of phenol from its aqueous solution on to fly ash obeys Freundlich isotherm. At a given temperature, from 10 mg g$^{-1}$ and 16 mg g$^{-1}$ aqueous phenol solutions, the concentrations of adsorbed phenol are measured to be 4 mg g$^{-1}$ and 10 mg g$^{-1}$, respectively. At this temperature, the concentration (in mg g$^{-1}$) of adsorbed phenol from 20 mg g$^{-1}$ aqueous solution of phenol will be ____. Use: $\log_{10} 2 = 0.3$
Monocyclic compounds $ P, Q, R $ and $ S $ are the major products formed in the reaction sequences given below.
The product having the highest number of unsaturated carbon atom(s) is:
- JEE Advanced - 2025
- Chemistry
- Organic Chemistry
For the reaction sequence given below, the correct statement(s) is(are):
- A linear octasaccharide (molar mass = 1024 g mol$^{-1}$) on complete hydrolysis produces three monosaccharides: ribose, 2-deoxyribose and glucose. The amount of 2-deoxyribose formed is 58.26 % (w/w) of the total amount of the monosaccharides produced in the hydrolyzed products. The number of ribose unit(s) present in one molecule of octasaccharide is _____.
Use: Molar mass (in g mol$^{-1}$): ribose = 150, 2-deoxyribose = 134, glucose = 180; Atomic mass (in amu): H = 1, O = 16- JEE Advanced - 2025
- Chemistry
- Biomolecules
Consider a reaction $ A + R \rightarrow Product $. The rate of this reaction is measured to be $ k[A][R] $. At the start of the reaction, the concentration of $ R $, $[R]_0$, is 10-times the concentration of $ A $, $[A]_0$. The reaction can be considered to be a pseudo first order reaction with assumption that $ k[R] = k' $ is constant. Due to this assumption, the relative error (in %) in the rate when this reaction is 40% complete, is ____. [$k$ and $k'$ represent corresponding rate constants]
- JEE Advanced - 2025
- Chemistry
- Chemical Kinetics
Top JEE Advanced Chemical Reactions Questions
- In the following reactions, P, Q, R, and S are the major products.
The correct statement(s) about P, Q, R, and S is(are)- JEE Advanced - 2023
- Chemistry
- Chemical Reactions
- LIST-I contains compounds and LIST-II contains reaction
LIST-I
LIST-II
I \(\text{H}_2\text{O}_2\) P \(\text{Mg(HCO}_3\text{)}_2 + \text{Ca(OH)}_2 \rightarrow \) II \(\mathrm{Mg(OH)_2}\) Q \(\text{BaO}_2 + \text{H}_2\text{SO}_4 \rightarrow \) III \(\text{BaCl}_2\) R \(\text{Ca(OH)}_2 + \text{MgCl}_2 \) IV \(\text{CaCO}_3\) S \(\text{BaO}_2 + 2\text{HCl} \rightarrow\) T \(\text{Ca(HCO}_3\text{)}_2 + 2\text{Ca(OH)}_2 \rightarrow \)
Match each compound in LIST – I with its formation reaction(s) in LIST-II, and choose the correct option- JEE Advanced - 2022
- Chemistry
- Chemical Reactions
- Which of the following liberates $O _{2}$ upon hydrolysis?
- JEE Advanced - 2020
- Chemistry
- Chemical Reactions
- The correct order of acid strength of the following carboxylic acids is
- JEE Advanced - 2019
- Chemistry
- Chemical Reactions
- In the reaction shown below, the major product(s) formed is/are
- JEE Advanced - 2014
- Chemistry
- Chemical Reactions
Top JEE Advanced Questions
- Adsorption of phenol from its aqueous solution on to fly ash obeys Freundlich isotherm. At a given temperature, from 10 mg g$^{-1}$ and 16 mg g$^{-1}$ aqueous phenol solutions, the concentrations of adsorbed phenol are measured to be 4 mg g$^{-1}$ and 10 mg g$^{-1}$, respectively. At this temperature, the concentration (in mg g$^{-1}$) of adsorbed phenol from 20 mg g$^{-1}$ aqueous solution of phenol will be ____. Use: $\log_{10} 2 = 0.3$
- JEE Advanced - 2025
- Adsorption
Monocyclic compounds $ P, Q, R $ and $ S $ are the major products formed in the reaction sequences given below.
The product having the highest number of unsaturated carbon atom(s) is:- JEE Advanced - 2025
- Organic Chemistry
For the reaction sequence given below, the correct statement(s) is(are):
- A linear octasaccharide (molar mass = 1024 g mol$^{-1}$) on complete hydrolysis produces three monosaccharides: ribose, 2-deoxyribose and glucose. The amount of 2-deoxyribose formed is 58.26 % (w/w) of the total amount of the monosaccharides produced in the hydrolyzed products. The number of ribose unit(s) present in one molecule of octasaccharide is _____.
Use: Molar mass (in g mol$^{-1}$): ribose = 150, 2-deoxyribose = 134, glucose = 180; Atomic mass (in amu): H = 1, O = 16- JEE Advanced - 2025
- Biomolecules
Consider a reaction $ A + R \rightarrow Product $. The rate of this reaction is measured to be $ k[A][R] $. At the start of the reaction, the concentration of $ R $, $[R]_0$, is 10-times the concentration of $ A $, $[A]_0$. The reaction can be considered to be a pseudo first order reaction with assumption that $ k[R] = k' $ is constant. Due to this assumption, the relative error (in %) in the rate when this reaction is 40% complete, is ____. [$k$ and $k'$ represent corresponding rate constants]
- JEE Advanced - 2025
- Chemical Kinetics
Concepts Used:
Haloalkanes and Haloarenes - Chemical Reactions
Chemical Reactions go with the breaking and bonding of covalent bonds which involve of exchange of electrons. The functional groups of Organic compounds play a consequential role in the process. Based on the above theory, reactions can be classified into five main groups:
Rearrangement Reactions are the type of reactions in which products get formed simply by the rearrangement of atoms and electrons in the reactant molecules.
O
||
NH4CNO → NH2 –C – NH2
Substitution Reactions are the reactions in which an atom or group of atoms is replaced by some other atom or group of atoms without any change in the structure of the remaining part of the molecule.
CH3Br + KOH (aqueous) → CH3OH + KBr
Addition Reactions are the reactions in which products get formed by the addition of some reagent to an unsaturated compound.
CH2 = CH2 + HCl → CH5Cl
- Electrophilic Addition Reactions
- Nucleophilic Addition Reactions
- Free Radical Addition Reactions
Elimination Reactions are the reactions in which the products get formed by the loss of simple molecules like HX from the reactant molecules.
C2H5OH → C2H4
- EN1 (Nucleophilic Elimination Unimolecular)
- EN2 (Nucleophilic Elimination Bimolecular)
A polymerization Reaction is the union of two or more molecules of a substance that form a single molecule with higher molecular weight.
n (CH = CH2) → (-CH2 – CH2 -) n