
Given that \( T \) is constant: \[ PV = \text{constant} \]
From this, we get the relation between pressure and volume: \[ P \propto \frac{1}{V} \]
If the volume changes by a factor of \( \frac{100}{101} \), the pressure changes by a factor of \( \frac{101}{100} \). Thus, the pressure becomes: \[ P_f = 1.01 \times P_0 \]
The equation for the pressure difference is: \[ P_0 - \frac{2T}{R} = 1.01 P_0 - \rho g h \]
Rearranging this to solve for \( \rho g h \): \[ \rho g h = 0.01 P_0 + \frac{2T}{R} \]
Now, substituting the given values: \[ (10^3)(10)h = (0.01)(10^5) + \frac{2 \times 0.075}{0.1 \times 10^{-3}} \]
Solving for \( h \): \[ h = \frac{2500}{10^4} \, \text{m} = 25 \, \text{cm} \]
A temperature difference can generate e.m.f. in some materials. Let $ S $ be the e.m.f. produced per unit temperature difference between the ends of a wire, $ \sigma $ the electrical conductivity and $ \kappa $ the thermal conductivity of the material of the wire. Taking $ M, L, T, I $ and $ K $ as dimensions of mass, length, time, current and temperature, respectively, the dimensional formula of the quantity $ Z = \frac{S^2 \sigma}{\kappa} $ is:
An ideal monatomic gas of $ n $ moles is taken through a cycle $ WXYZW $ consisting of consecutive adiabatic and isobaric quasi-static processes, as shown in the schematic $ V-T $ diagram. The volume of the gas at $ W, X $ and $ Y $ points are, $ 64 \, \text{cm}^3 $, $ 125 \, \text{cm}^3 $ and $ 250 \, \text{cm}^3 $, respectively. If the absolute temperature of the gas $ T_W $ at the point $ W $ is such that $ n R T_W = 1 \, J $ ($ R $ is the universal gas constant), then the amount of heat absorbed (in J) by the gas along the path $ XY $ is 



A soft plastic bottle, filled with water of density 1 gm/cc, carries an inverted glass test tube with some air (ideal gas) trapped as shown in the figure. The test tube has a mass of 5 gm, and it is made of a thick glass of density 2.5 gm/cc. Initially, the bottle is sealed at atmospheric pressure p0 = 105 Pa so that the volume of the trapped air is V0 = 3.3 cc. When the bottle is squeezed from outside at a constant temperature, the pressure inside rises and the volume of the trapped air reduces. It is found that the test tube begins to sink at pressure p0 + Δp without changing its orientation. At this pressure, the volume of the trapped air is V0 – ΔV.
Let ΔV = X cc and Δp = Y × 103 Pa.
Monocyclic compounds $ P, Q, R $ and $ S $ are the major products formed in the reaction sequences given below.
The product having the highest number of unsaturated carbon atom(s) is:
For the reaction sequence given below, the correct statement(s) is(are): 
Consider a reaction $ A + R \rightarrow Product $. The rate of this reaction is measured to be $ k[A][R] $. At the start of the reaction, the concentration of $ R $, $[R]_0$, is 10-times the concentration of $ A $, $[A]_0$. The reaction can be considered to be a pseudo first order reaction with assumption that $ k[R] = k' $ is constant. Due to this assumption, the relative error (in %) in the rate when this reaction is 40% complete, is ____. [$k$ and $k'$ represent corresponding rate constants]
The science of the mechanical properties of fluids is called Hydrostatics. A fluid is a substance that relents to the slightest pressure. Fluids are categorized into two classes famed by the names of liquids, and elastic fluids or gases, which later comprehend the air of the atmosphere and all the different kinds of air with which chemistry makes us acquainted.
A streamline is a curve the tangent to which at any point provides the direction of the fluid velocity at that point. It is comparable to a line of force in an electric or magnetic field. In steady flow, the pattern of the streamline is motionless or static with time, and therefore, a streamline provides the actual path of a fluid particle.
A tubular region of fluid enclosed by a boundary comprises streamlines is called a tube of flow. Fluid can never cross the boundaries of a tube of flow and therefore, a tube of flow acts as a pipe of the same shape.
The surface tension of a liquid is all the time a function of the solid or fluid with which the liquid is in contact. If a value for surface tension is provided in a table for oil, water, mercury, or whatever, and the contacting fluid is unspecified, it is safe to consider that the contacting fluid is air.