Question:

An example of a liquid metal mixture which produces near ideal solutions is:

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Ideal liquid solutions form when A–A, B–B, and A–B interactions are similar.
Updated On: Jun 29, 2026
  • Copper - Magnesium
  • Bismuth - Cadmium
  • Iron - Silver
  • Bismuth - Tin
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The Correct Option is B

Solution and Explanation

Concept: An ideal solution obeys Raoult’s law: \[ P_A = X_A P_A^0, \quad P_B = X_B P_B^0 \] Conditions for ideality:
• Similar atomic size
• Similar bonding nature
• No heat of mixing
• No volume change

Step 1:
Check given systems.

• Bi–Cd system shows nearly ideal liquid behavior
• Cu–Mg → strong interaction difference
• Fe–Ag → immiscible tendency
• Bi–Sn → strong deviation from ideality

Step 2:
Reason for Bi–Cd ideality.
In Bi–Cd:
• atomic sizes are comparable
• interaction energies are similar
• no strong compound formation Thus behaves nearly ideally in liquid state. Final Answer: \[ \boxed{\text{Bismuth - Cadmium}} \]
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