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an example of a liquid metal mixture which produce
Question:
An example of a liquid metal mixture which produces near ideal solutions is:
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Ideal liquid solutions form when A–A, B–B, and A–B interactions are similar.
TS PGECET - 2026
TS PGECET
Updated On:
Jun 29, 2026
Copper - Magnesium
Bismuth - Cadmium
Iron - Silver
Bismuth - Tin
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The Correct Option is
B
Solution and Explanation
Concept:
An ideal solution obeys Raoult’s law: \[ P_A = X_A P_A^0, \quad P_B = X_B P_B^0 \] Conditions for ideality:
• Similar atomic size
• Similar bonding nature
• No heat of mixing
• No volume change
Step 1:
Check given systems.
• Bi–Cd system shows nearly ideal liquid behavior
• Cu–Mg → strong interaction difference
• Fe–Ag → immiscible tendency
• Bi–Sn → strong deviation from ideality
Step 2:
Reason for Bi–Cd ideality.
In Bi–Cd:
• atomic sizes are comparable
• interaction energies are similar
• no strong compound formation Thus behaves nearly ideally in liquid state.
Final Answer:
\[ \boxed{\text{Bismuth - Cadmium}} \]
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