2Al + 3H2SO4 → Al2(SO4)3 + 3H2
Mole of Al taken = \(\frac{5.4 }{ 27}\) = 0.2
Mole of H2SO4 taken = \(\frac{{50 \times 5}}{{1000}} = 0.25\)
As \(\frac{0.2}{2} > \frac{0.25}{3}, \text{H}_2\text{SO}_4\) is limiting reagent
Now, moles of H2 formed = \(\frac{3}{3} \times 0.25 = 0.25\)
Therefore Volume =\(0.25 \times 0.082 \times \frac{300}{1} = \frac{24.6}{4} = 6.15 \, \text{L}\)


| List-I | List-II | ||
| (P) | (-)-1-Bromo-2-ethylpentane ![]() (single enantiomer) | (1) | Inversion of configuration |
| (Q) | (-)-2-Bromopentane ![]() (single enantiomer) | (2) | Retention of configuration |
| (R) | (-)-3- Bromo-3-methylhexane ![]() (single enantiometer) | (3) | Mixture of enantiomers |
| (S) | ![]() (single enantiometer) | (4) | Mixture of structural isomers |
| (5) | Mixture of diastereomers |
Match the reactions (in the given stoichiometry of the reactants) in List-I with one of their products given in List-II and choose the correct option.
List-I | List-II | ||
| (P) | P2O3 + 3H2O → | (1) | P(O)(OCH3)Cl2 |
| (Q) | P4 + 3NaOH + 3H2O → | (2) | H3PO3 |
| (R) | PCl5 + CH3COOH → | (3) | PH3 |
| (S) | H3PO2 + 2H2O + 4AgNO3 → | (4) | POCl3 |
| (5) | H3PO4 |
| List-I | List-II | ||
| (P) | \(t^6_{2g} e^0_g\) | (1) | \( [Fe(H_2O)_6]^{2+}\) |
| (Q) | \(t^3_{2g} e^2_g\) | (2) | \( [Mn(H_2O)_6]^{2+}\) |
| (R) | \(e^2t^3_{2}\) | (3) | \( [Co(NH_3)_6]^{3+}\) |
| (S) | \(t^4_{2g} e^2_g\) | (4) | \([FeCl_4]^-\) |
| (5) | \( [CoCl_4]^{2-}\) |