The specific volume of the mixture is given by:
\[
v_{\text{mix}} = v_f + x \cdot (v_g - v_f),
\]
where:
- \( v_f = 0.001084 \, \text{m³/kg} \) is the specific volume of the saturated liquid,
- \( v_g = 0.46242 \, \text{m³/kg} \) is the specific volume of the saturated vapour,
- \( x = 0.80 \) is the quality of the mixture (80% vapour).
Thus, the specific volume of the mixture is:
\[
v_{\text{mix}} = 0.001084 + 0.80 \cdot (0.46242 - 0.001084) = 0.001084 + 0.369888 = 0.370972 \, \text{m³/kg}.
\]
Now, the total mass of the mixture is:
\[
m = \frac{V}{v_{\text{mix}}} = \frac{50}{0.370972} \approx 134.8 \, \text{kg}.
\]
Thus, the total mass of the liquid-vapour mixture in the tank is:
\[
\boxed{134 \, \text{to} \, 136 \, \text{kg}}.
\]