Step 1: Calculate the total horizontal distance (width) of the pit.
\[
{Total width} = 24 \, {m} + (4 \times 10 \, {m}) = 24 \, {m} + 40 \, {m} = 64 \, {m}
\]
Step 2: Calculate the total height of the pit.
\[
{Total height} = 5 \times 8 \, {m} = 40 \, {m}
\]
Step 3: Calculate the overall slope angle.
\[
\tan(\theta) = \frac{{Total height}}{{Total width}} = \frac{40 \, {m}}{64 \, {m}} = 0.625
\]
\[
\theta = \tan^{-1}(0.625) \approx 32.47^\circ
\]
Thus, the overall pit slope angle is approximately \( \boxed{32.47^\circ} \).