The standard deviation of the critical path in a PERT network is calculated by summing the variances of each activity on the critical path.
Since the standard deviation for each activity is given as 3, the variance for each activity is \( 3^2 = 9 \).
The total variance of the critical path is the sum of the variances of all 9 activities, so:
\[
\text{Total variance} = 9 \times 9 = 81
\]
Thus, the standard deviation of the critical path is the square root of 81:
\[
\text{Standard deviation} = \sqrt{81} = 9
\]
Therefore, the correct answer is (B).