Step 1: Mass of waste routed to RDF.
Fraction to RDF $=25%$ of 1000 t/d $\Rightarrow 250$ t/d of feed to the RDF process.
Process efficiency $=80%$ $\Rightarrow$ RDF actually produced $=0.80\times 250=200$ t/d.
\[
200\ \text{t/d}=200{,}000\ \text{kg/d}.
\]
Step 2: Daily thermal energy in the RDF.
\[
E_{\text{thermal}}= \text{mass}\times \text{CV}=200{,}000\ \text{kg/d}\times 15\ \text{MJ/kg}=3{,}000{,}000\ \text{MJ/d}.
\]
Step 3: Convert thermal energy to electrical energy (20% efficiency).
\[
E_{\text{elec}}=0.20\times 3{,}000{,}000=600{,}000\ \text{MJ/d}.
\]
Step 4: Convert MJ to MWh.
$1\ \text{kWh}=3.6\ \text{MJ}\Rightarrow 1\ \text{MWh}=3600\ \text{MJ}$. Hence,
\[
E_{\text{elec}}=\frac{600{,}000\ \text{MJ/d}}{3.6\ \text{MJ/kWh}}=166{,}666.7\ \text{kWh/d}=166.67\ \text{MWh/d}.
\]
Final Answer:
\[
\boxed{166.67\ \text{MWh/d}}
\]