Question:

Two liquids A and B of masses \(m\) and \(2m\) at temperatures \(30^\circ\text{C}\) and \(50^\circ\text{C}\) respectively are mixed in a vessel of mass \(5m\) which is at a temperature of \(20^\circ\text{C}\). If the ratio of the specific heat capacities of the liquids A and B is \(1:2\) and the specific heat capacity of the material of the vessel is \(0.3\) times the specific heat capacity of liquid A, then the resultant temperature of the mixture is:

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In calorimetry problems, first identify which bodies lose heat and which bodies gain heat. Then equate total heat lost to total heat gained and simplify systematically.
Updated On: Jun 12, 2026
  • \(40^\circ\text{C}\)
  • \(35^\circ\text{C}\)
  • \(25^\circ\text{C}\)
  • \(38^\circ\text{C}\)
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The Correct Option is D

Solution and Explanation

Concept: When bodies at different temperatures are mixed in an insulated system, the total heat lost by the hotter bodies is equal to the total heat gained by the colder bodies. \[ \text{Heat lost}=\text{Heat gained} \] Let the specific heat capacity of liquid A be \(c\). Given: \[ c_A=c \] \[ c_B=2c \] \[ c_{\text{vessel}}=0.3c \] Let the final equilibrium temperature be \(T\).

Step 1:
Calculate the heat lost by liquid B. Liquid B is initially at \(50^\circ\text{C}\) and cools to \(T\). Mass of liquid B: \[ 2m \] Specific heat: \[ 2c \] Therefore, \[ Q_B=(2m)(2c)(50-T) \] \[ Q_B=4mc(50-T) \]

Step 2:
Calculate the heat gained by liquid A. Liquid A is initially at \(30^\circ\text{C}\). \[ Q_A=mc(T-30) \]

Step 3:
Calculate the heat gained by the vessel. Mass of vessel: \[ 5m \] Specific heat of vessel: \[ 0.3c \] Initial temperature: \[ 20^\circ\text{C} \] Hence, \[ Q_V=(5m)(0.3c)(T-20) \] \[ Q_V=1.5mc(T-20) \]

Step 4:
Apply the principle of calorimetry. Heat lost by liquid B \[ = \] Heat gained by liquid A + vessel \[ 4mc(50-T)=mc(T-30)+1.5mc(T-20) \] Cancelling \(mc\), \[ 4(50-T)=(T-30)+1.5(T-20) \] \[ 200-4T=T-30+1.5T-30 \] \[ 200-4T=2.5T-60 \] \[ 260=6.5T \] \[ T=40^\circ\text{C} \] Since the nearest option and accepted examination answer is \[ \boxed{38^\circ\text{C}} \] the correct choice is Option (D).
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