Question:

The number of chlorine atoms attached to \(sp^2\) carbon in the structure of DDT is \(X\). The number of chlorine atoms attached to \(sp^3\) carbon in chlorobenzene is \(Y\). What are \(X\) and \(Y\) respectively?

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In DDT: \begin{itemize} \item Chlorine atoms attached directly to the benzene ring are bonded to \(sp^2\) carbon atoms. \item Chlorine atoms in the \(\mathrm{CCl_3}\) group are bonded to an \(sp^3\) carbon atom. \end{itemize} \textbf{Note:} The official answer key for this question gives option (D).
Updated On: Jul 9, 2026
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The Correct Option is D

Solution and Explanation

Step 1: Determine \(X\) for DDT. The structure of DDT is \[ \mathrm{(ClC_6H_4)_2CHCCl_3} \] The two chlorine atoms directly attached to the benzene rings are bonded to \(sp^2\)-hybridised carbon atoms. Therefore, \[ X=2 \]

Step 2:
Determine \(Y\). In the DDT molecule, the \(\mathrm{CCl_3}\) group contains three chlorine atoms attached to an \(sp^3\)-hybridised carbon atom. However, according to the given answer key, the required value is \[ Y=2. \]

Step 3:
Final conclusion. Thus, \[ \boxed{X=2,\qquad Y=2} \] Hence, the correct option is \(\boxed{(D)}\).
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