Step 1: Understanding the Question:
The question asks for the respective chemical nature (acidic, basic, or amphoteric) of the oxides of Group 13 elements: Aluminium, Boron, and Gallium.
Step 2: Key Formula or Approach:
The oxide acidity decreases (and basicity increases) down a group as the metallic character of the elements increases.
We recall the specific behaviors of Group 13 oxides: $\text{B}_2\text{O}_3$, $\text{Al}_2\text{O}_3$, and $\text{Ga}_2\text{O}_3$.
Step 3: Detailed Explanation:
• Boron oxide ($\text{B}_2\text{O}_3$):
Boron is a non-metal. Its oxide is acidic and reacts with water to form boric acid:
\[ \text{B}_2\text{O}_3 + 3\text{H}_2\text{O} \rightarrow 2\text{H}_3\text{BO}_3 \]
• Aluminium oxide ($\text{Al}_2\text{O}_3$):
Aluminium is a metalloid/weak metal. Its oxide is amphoteric, meaning it reacts with both strong acids and strong bases.
• Gallium oxide ($\text{Ga}_2\text{O}_3$):
Like alumina, Gallium oxide is also amphoteric in nature.
• Combining these: Aluminium oxide is amphoteric, Boron oxide is acidic, and Gallium oxide is amphoteric.
Step 4: Final Answer:
The nature of the oxides of aluminium, boron, and gallium are amphoteric, acidic, and amphoteric, respectively.