Step 1: Recall the storage organs.
In Dioscorea (yam), food is stored in
\[
\boxed{\text{vegetative buds (bulbils).}}
\]
In Agave, food is stored in
\[
\boxed{\text{floral buds (bulbils).}}
\]
Step 2: Identify the correct combination.
Thus, the correct combination is
\[
\boxed{
\text{Dioscorea} \rightarrow \text{Vegetative buds},\qquad
\text{Agave} \rightarrow \text{Floral buds}.
}
\]
Step 3: Choose the correct option.
Hence, the correct option is
\[
\boxed{(D).}
\]