Concept:
In Bohr's model of Hydrogen atom,
\[
r_n \propto n^2,
\qquad
v_n \propto \frac{1}{n}.
\]
Therefore, the time period of revolution is
\[
T_n=\frac{2\pi r_n}{v_n}
\propto n^3.
\]
Also, the angular momentum in the \(n^{\text{th}}\) orbit is
\[
L_n=\frac{nh}{2\pi}.
\]
Step 1: Determine the orbit number \(n\).
Given,
\[
T_1:T_n=1:64.
\]
Since
\[
T_n\propto n^3,
\]
\[
\frac{T_n}{T_1}=n^3=64.
\]
\[
n=4.
\]
Step 2: Find the orbit corresponding to the \(n^{\text{th}}\) excited state.
The \(n^{\text{th}}\) excited state corresponds to orbit number
\[
n+1.
\]
Since \(n=4\),
\[
\text{orbit number}=5.
\]
Step 3: Calculate the angular momentum.
\[
L=\frac{5h}{2\pi}.
\]
\[
L=\frac{2.5h}{\pi}.
\]
Step 4: Write the final answer.
\[
\boxed{L=\frac{5h}{2\pi}}
\]
\[
\boxed{L=\frac{2.5h}{\pi}}
\]
\[
\boxed{\text{Answer = (C)}}
\]